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methyl isothiocyanate : ウィキペディア英語版
methyl isothiocyanate

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Methyl isothiocyanate is the organosulfur compound with the formula CH3N=C=S. This low melting colorless solid is a powerful lachrymator. As a precursor to a variety of valuable bioactive compounds, it is the most important organic isothiocyanate in industry.
==Synthesis==
It is prepared industrially by two routes. Annual production in 1993 was estimated to be 4M kg. The main method involves the thermal rearrangement of methyl thiocyanate:〔
:CH3S-C≡N → CH3N=C=S
It is also prepared via with the reaction of methylamine with carbon disulfide followed by oxidation of the resulting dithiocarbamate with hydrogen peroxide. A related method is useful to prepare this compound in the laboratory.
MITC forms naturally upon the enzymatic degradation of glucocapparin, a modified sugar found in capers.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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